Effect of artificial maturation on carbazole distributions, as revealed bythe hydrous pyrolysis of an organic-sulphur-rich source rock (Ghareb Formation, Jordan)
H. Clegg et al., Effect of artificial maturation on carbazole distributions, as revealed bythe hydrous pyrolysis of an organic-sulphur-rich source rock (Ghareb Formation, Jordan), ORG GEOCHEM, 29(8), 1998, pp. 1953-1960
Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper
Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock
, using a temperature range of 200 to 360 degrees C (72 h). The original se
diment contains only low amounts of carbazoles, (maximum 2.2 mu g/g bitumen
for 1-methylcarbazole). With increasing thermal maturation, intense genera
tion begins at temperatures only in excess of 300 degrees C, reaching a max
imum at 360 degrees C. Likewise, during natural maturation, generation occu
rs at later stages of maturity (e.g. for Tithonian source rocks at > 0.81%
R-r and for Posidonia Shale at >0.88% R-r). Some isomeric changes during hy
drous pyrolysis do not resemble those in nature whereas others do. The rela
tive abundances of selected C-1- and C-2-alkylcarbazoles on ternary diagram
s reveal differences, whereas the benzo[a]carbazole/benzo [a]carbazole + be
nzo [c]carbazole ratio is closely similar. The latter result supports the c
ontention that maturation plays a key role in controlling carbazole distrib
utions in source rocks. However, the results for alkylcarbazoles, especiall
y the C-2-carbazoles, are not easy to interpret. (C) 1998 Elsevier Science
Ltd. All rights reserved.