Specificity of interionic contacts and estimation of average interionic distances by NOE NMR measurements in solution of cationic Ru(II) organometallic complexes bearing unsymmetrical counterions

Authors
Zuccaccia, C Bellachioma, G Cardaci, G Macchioni, A
Citation
C. Zuccaccia et al., Specificity of interionic contacts and estimation of average interionic distances by NOE NMR measurements in solution of cationic Ru(II) organometallic complexes bearing unsymmetrical counterions, ORGANOMETAL, 18(1), 1999, pp. 1-3
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
1
Year of publication
1999
Pages
1 - 3
Database
ISI
SICI code
0276-7333(19990104)18:1<1:SOICAE>2.0.ZU;2-X
Abstract
The interionic structure in methylene chloride of trans-[Ru(PMe3)(2)(CO)(CO Me)(CH2-pz(2))]BPh3R (where pz = pyrazolyl ring; R = Me, n-Bu, n-Hex and Ph ) complex es has been investigated by the detection of interionic contacts in H-1 NOESY NMR spectra. We observed an unexpected specificity of interion ic contacts that allowed, for the first time, the estimation of reasonable average interionic distances by measuring the kinetic of H-1 NOE buildup.