We construct an effective Lagrangian for interacting pions with non-relativ
istic energies. The coupling constants can be expressed in terms of the dif
ferent scattering lengths and slopes. When used in the calculation of the p
ionium decay rate, the scattering slope contribution gives a correction of
about 8% compared with the lowest order contribution coming from the scatte
ring lengths alone. [S0556-2821(98)07623-1].