While the use of continuum approximations to describe systems consisting of
many molecules is well established, it is not known how such approximation
s fail as the number of molecular components decreases. We study the one-di
mensional Fermi-Pasta-Ulam chain in order to determine the critical Value o
f the system size below which the system's behavior deviates from the conti
nuum limit, allowing us to delineate between "small" and "large" systems an
d define these terms precisely. For this system, the distinction between sm
all and large is correlated with the appearance of an instability of the ch
ain.