Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates

Authors
Semioshkin, AA Inyushin, SG Ermanson, LV Petrovskii, PV Lemmen, P Bregadze, VI
Citation
Aa. Semioshkin et al., Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates, RUSS CHEM B, 47(10), 1998, pp. 1985-1988
Citations number
15
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
1985 - 1988
Database
ISI
SICI code
1066-5285(199810)47:10<1985:IOCEWT>2.0.ZU;2-D
Abstract
The reactions of o-carboran-1-ylethyl mesylates with triethyl phosphite and sodium diethyl phosphite were studied. Carborane-containing phosphonates w ere synthesized. The reaction of o-carboranylacetyl chloride with triethyl phosphite afforded O,O-diethyl (E)-2-(o-carboran-1-yl)-1 -(o-carboran-1-yla cetoxy)vinylphosphonate rather than oxo phosphonate.