Synthesis, spectral characteristics, and crystal structure of the hexanuclear complex MeSi[eta(1),eta(5)-C5H4(CO)(2)Fe(eta(1),eta(5)-C5H4)Mn(CO)(3)](3)

Authors
Orlova, TY Nekrasov, YS Petrovskii, PV Ezernitskaya, MG Starikova, ZA Yanovksy, AI
Citation
Ty. Orlova et al., Synthesis, spectral characteristics, and crystal structure of the hexanuclear complex MeSi[eta(1),eta(5)-C5H4(CO)(2)Fe(eta(1),eta(5)-C5H4)Mn(CO)(3)](3), RUSS CHEM B, 47(10), 1998, pp. 2000-2006
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
2000 - 2006
Database
ISI
SICI code
1066-5285(199810)47:10<2000:SSCACS>2.0.ZU;2-O
Abstract
The reaction of MeSiCl3 with 3 equivalents of LiC5H4(CO)(2)Fe(eta(1),eta(5) -C5H4)Mn(Co)(3) afforded the hexanuclear complex MeSi[eta(1),eta(5)-C5H4(CO )(2)Fe(eta(1),eta(5)-C5H4)Mn(CO)(3)](3). The structure of the resulting com plex was established by H-1 and C-13 NMR and IR spectroscopy and by X-ray d iffraction analysis.