Catalytic activity of various Lewis acids in the phosphorylation of primary polyfluoroalkanols with phosphoryl chloride

Authors
Kudryavtsev, IY Zakharov, LS Kabachnik, MI
Citation
Iy. Kudryavtsev et al., Catalytic activity of various Lewis acids in the phosphorylation of primary polyfluoroalkanols with phosphoryl chloride, RUSS CHEM B, 47(10), 1998, pp. 2015-2016
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
2015 - 2016
Database
ISI
SICI code
1066-5285(199810)47:10<2015:CAOVLA>2.0.ZU;2-J
Abstract
The catalytic activity of SnCl2, SnCl4, SbCl3, SbCl5, and BiCl3 in the reac tion of 2,2,3,3,4,4,4-heptafluorobutanol with POCl3 was studied. The mechan ism of this reaction is discussed. Strong Lewis acids were found to be less active catalysts.