Reduction of carbon monoxide by molybdenum-containing hydroxide systems

Authors
Denisov, NT Mironova, SA Shuvalova, NI Shilov, AE
Citation
Nt. Denisov et al., Reduction of carbon monoxide by molybdenum-containing hydroxide systems, RUSS CHEM B, 47(10), 1998, pp. 2025-2027
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
2025 - 2027
Database
ISI
SICI code
1066-5285(199810)47:10<2025:ROCMBM>2.0.ZU;2-9
Abstract
The reduction of CO by the nitrogen-fixing systems Ti(OH)(3)-Mo(OH)(3) and MgTi2O4-Mo(OH)(3) was studied in aqueous and water-methanol media; in the l atter, (CO)-C-14 was used as the reagent. The main reaction product is meth anol, whose yield in the H2O-MeOH-KOH mixture is almost an order of magnitu de higher than that in an aqueous alkaline solution. The data obtained were compared to those for the reduction of N-2.