Reactions of terminal acylacetylenes with thiocarbohydrazones

Citation
Tn. Komarova et al., Reactions of terminal acylacetylenes with thiocarbohydrazones, RUSS CHEM B, 47(10), 1998, pp. 2027-2029
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
2027 - 2029
Database
ISI
SICI code
1066-5285(199810)47:10<2027:ROTAWT>2.0.ZU;2-L
Abstract
The reactions of terminal acylacetylenes with thiocarbohydrazones give 2-(2 -acyl-vinyl)thiocarbohydrazones or 2,2-bis(2-acylvinyl)thiocarbohydrazones depending on the reagent ratio. Benzoylacetylene reacts with thiocarbohydra zone of p-dimethylaminobenzaldehyde to form S-[2-(p-dimethylaminobenzoyl)vi nyl]isothiocarbodihydrazone.