The role of hydrogen atoms in CIDNP effects in the reaction of diisobutylaluminum hydride with CCl4

Authors
Sadykov, RA Teregulov, IK
Citation
Ra. Sadykov et Ik. Teregulov, The role of hydrogen atoms in CIDNP effects in the reaction of diisobutylaluminum hydride with CCl4, RUSS CHEM B, 47(10), 1998, pp. 2040-2042
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
10
Year of publication
1998
Pages
2040 - 2042
Database
ISI
SICI code
1066-5285(199810)47:10<2040:TROHAI>2.0.ZU;2-D
Abstract
Integral polarization of chloroform, methylene dichloride, and pentachloroe thane was observed in the IH NMR spectra during the exothermal reaction of a 1 M solution of (Bu2AlH)-Al-i in 1,4-dioxane with CCl4. CIDNP was shown t o appear in the diffusion radical pair of the hydrogen atom and trichlorome thyl radical.