Triethylborane-induced radical addition of halogenated compounds to alkenes and alkynes in water

Authors
Nakamura, T Yorimitsu, H Shinokubo, H Oshima, K
Citation
T. Nakamura et al., Triethylborane-induced radical addition of halogenated compounds to alkenes and alkynes in water, SYNLETT, (12), 1998, pp. 1351-1352
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
12
Year of publication
1998
Pages
1351 - 1352
Database
ISI
SICI code
0936-5214(199812):12<1351:TRAOHC>2.0.ZU;2-J
Abstract
Treatment of a mixture of alpha-iodo-gamma-butyrolactone and phenylacetylen e in water with a-catalytic amount of triethylborane provided the correspon ding adduct in good yield via intermolecular radical addition reaction. The triethylborane-mediated radical reaction in aqueous media could be perform ed under acidic or basic conditions.