Stereoselective synthesis of alpha-C-glucosamines via anomeric organosamarium reagents

Citation
L. Andersen et al., Stereoselective synthesis of alpha-C-glucosamines via anomeric organosamarium reagents, SYNLETT, (12), 1998, pp. 1393-1395
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
12
Year of publication
1998
Pages
1393 - 1395
Database
ISI
SICI code
0936-5214(199812):12<1393:SSOAVA>2.0.ZU;2-N
Abstract
The direct coupling of the pyridyl sulfone of N-acetylglucosamine with alde hydes or ketones is promoted by samarium diiodide affording the correspondi ng alpha-C-glycosides preferentially. A C-disaccharide has been synthesized using this approach.