Synthetic studies of moenomycin A disaccharide analogues. Protection of the anomeric centre with long-chain protective groups

Citation
D. Weigelt et al., Synthetic studies of moenomycin A disaccharide analogues. Protection of the anomeric centre with long-chain protective groups, TETRAHEDRON, 55(3), 1999, pp. 687-698
Citations number
26
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
3
Year of publication
1999
Pages
687 - 698
Database
ISI
SICI code
0040-4020(19990115)55:3<687:SSOMAD>2.0.ZU;2-J
Abstract
Two new C-9 protecting groups for the anomeric position of carbohydrates ar e reported. Methods both for their introduction and removal are described. The C-9-protected compounds are much less polar than the corresponding ally l protected analogues. The new protecting group chemistry has been used to prepare compound 17 en route to a disaccharide analogue of the antibiotic m oenomycin A. (C) 1998 Elsevier Science Ltd. All rights reserved.