Hydroboration of the amino(imino)borane [Me3C(Me3Si)N]B[N(CMe3)]

Authors
Bulak, E Varnah, T Paetzold, P Englert, U
Citation
E. Bulak et al., Hydroboration of the amino(imino)borane [Me3C(Me3Si)N]B[N(CMe3)], Z ANORG A C, 625(1), 1999, pp. 3-5
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
1
Year of publication
1999
Pages
3 - 5
Database
ISI
SICI code
0044-2313(199901)625:1<3:HOTA[>2.0.ZU;2-1
Abstract
The formation of four products of the type Me3C(Me3Si)N=BH-N(CMe3)=BR2' [BR 2' = B(CHMeiPr)(2) (1), B(c-C6H11)(2) (2), B(C8H14) (3), B(O2C6H4) (4)] fro m the iminoborane Me3C(Me3Si)N - B double bond N(CMe3) and the hydroboranes (R-2'BH)(2) is described. Crystal structure analysis reveals the molecule 1 to have an N=B-N=B backbone with two orthogonal N=B bond planes and, henc e, no conjugation between the two B-N double bonds.