Authors
Citation
Ms. Wickleder, Eu(ClO4)(3): First single crystals of an anhydrous rare-earth perchlorate, Z ANORG A C, 625(1), 1999, pp. 11-12
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313
→ ACNP
Volume
625
Issue
1
Year of publication
1999
Pages
11 - 12
Database
ISI
SICI code
0044-2313(199901)625:1<11:EFSCOA>2.0.ZU;2-3
Abstract
Single crystals of Eu(ClO4)(3) have been obtained by slow dehydration of a
hydrous product prepared by the reaction of Eu2O3 with HClO4. The crystal s
tructure (hexagonal, P6(3)/m, Z = 2, a = 924.96(9), c = 574.86(8) pm) consi
sts of tricapped trigonal [EuO9] prisms and [ClO4] tetrahedra. One of the o
xygen atoms in the ClO4 group does not coordinate to Eu3+ and points toward
s the empty channel which runs in the direction [001].