Preparation, spectroscopic characterization, and crystal structure of (CF3)(2)C(F)OH2+Sb2F11-

Authors
Minkwitz, R Reinemann, S
Citation
R. Minkwitz et S. Reinemann, Preparation, spectroscopic characterization, and crystal structure of (CF3)(2)C(F)OH2+Sb2F11-, Z ANORG A C, 625(1), 1999, pp. 121-125
Citations number
49
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
1
Year of publication
1999
Pages
121 - 125
Database
ISI
SICI code
0044-2313(199901)625:1<121:PSCACS>2.0.ZU;2-4
Abstract
Hexafluoroacetone, (CF3)(2)CO, reacts at -78 degrees C with the superacid H F/SbF5 under formation of the primary oxonium salt, (CF3)(2)C(F)OH2+Sb2F11- , which is characterized by vibrational spectroscopy and NMR spectra. The s alt crystallizes in the triclinic space group P (1) over bar with a = 817.9 (1), b = 989.0(1), c = 1003.8(1) pm and 2 formula units per unit cell.