The conversion of the C6 saturated hydrocarbons hexane, methylcyclopentane
and cyclohexane was studied in a flow microreactor in the temperature range
120-240 degrees C. Sulfated zirconia with different sulfate contents were
used as catalysts. Catalysts were characterized before and after reactant e
xposure using Raman spectroscopy and XPS. The obtained results confirm data
on the reaction mechanism already reported in the literature. The first st
ep is the hydrogen abstraction which could occur to a more or less advanced
extent as a function of the sulfate density species. This process is the m
ain cause of the catalyst reactivity but also of the catalyst deactivation.
More advanced dehydrogenated species lead to polymerized species which rem
ain strongly chemisorbed on the catalyst surface. XPS data also indicated t
hat during these redox processes a part of the sulfur remained on the catal
ysts surface. Higher sulfate densities lead to the cyclization of hexane. (
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