Aggregation/deaggregation processes in vanadium(II) carboxylate chemistry

Authors
Bonitatebus, PJ Armstrong, WH
Citation
Pj. Bonitatebus et Wh. Armstrong, Aggregation/deaggregation processes in vanadium(II) carboxylate chemistry, CHEM COMMUN, (1), 1999, pp. 55-56
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
1
Year of publication
1999
Pages
55 - 56
Database
ISI
SICI code
1359-7345(19990107):1<55:APIVCC>2.0.ZU;2-8
Abstract
Reactions of potassium tris(3,5-dimethylpyrazolyl)borate (KTpb(Me2)) with t he low-valent mixed-metal complex [(thf)(3)V(mu-Cl)(mu-tfa)(2)V(thf)(3)] [Z nCl3(thf)] resulted first in ZnCl+ abstraction and tetramer formation, then in asymmetric binuclear product formation through ligand substitution.