A family of recently developed techniques is explored for achieving both ma
trix sparsity and rapid convergence when numerically solving differential a
nd eigenvalue equations without domain decomposition. These methods, which
we call spectral differences, include Boyd's sum acceleration techniques an
d the Lagrange distributed approximating functional (LDAF) approach. A form
ula is developed for estimating the unknown Gaussian parameter within LDAF.
We implement these methods to calculate the Morse vibrational energies for
diatomic iodine. For equivalent bandwidths the sum acceleration with finit
e difference weights generates energies which are between two and three ord
ers of magnitude more accurate than those from LDAF. (C) 1999 Elsevier Scie
nce B.V. All rights reserved.