Evaluation of an improved volume translation for the prediction of hydrocarbon volumetric properties

Citation
Hb. De Sant'Ana et al., Evaluation of an improved volume translation for the prediction of hydrocarbon volumetric properties, FLU PH EQUI, 154(2), 1999, pp. 193-204
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
FLUID PHASE EQUILIBRIA
ISSN journal
03783812 → ACNP
Volume
154
Issue
2
Year of publication
1999
Pages
193 - 204
Database
ISI
SICI code
0378-3812(19990125)154:2<193:EOAIVT>2.0.ZU;2-R
Abstract
In the present study the volume translation expression of Ungerer and Batut that is a function of the temperature and molecular weight was evaluated. Instead of being calibrated on the saturated liquid densities, this correla tion uses high pressure liquid densities. As a result, it is less sensitive to the inconsistencies shown by other correlations, due to the proximity o f the critical region. The mentioned expression is compared to experimental data and with correlations presented by Jhaveri and Youngren, Soreide and Magoulas and Tassios, providing a good prediction of molar volumes at high temperature and pressure and reasonable saturated liquid densities. (C) 199 9 Elsevier Science B.V. All rights reserved.