An extremely high quantum photoyield, as high as 70% at the photon energy o
f 10 eV, was observed from cesiated polycrystalline diamond films. The thre
shold photon energy of 5.5 eV or less was observed. The results suggest tha
t the cesiated polycrystalline diamond surface has a true negative electron
affinity. In contrast, a quantum photoyield of 17% at the photon energy of
10 eV was observed for a hydrogenated polycrystalline diamond film. The th
reshold photon energy of 5.5 eV or less was also observed, as in the cesiat
ed one. It seems that the hydrogenated polycrystalline diamond surface has
an effective negative electron affinity.