After outlining the general characteristics of high-energy ball-milling, me
chanochemical synthesis is argued to be an attractive method for the synthe
sis and transformation of materials. Phase transformations induced by milli
ng, annealing of mechanically activated iron silicides, mechanically activa
ted self-heal sustaining reactions (MASHS), for instance of FeAl, are first
discussed. The route, which starts from mechanosynthesized powders to reac
h consolidated alumina-( Fe,Ti) composites, yields materials whose original
morphologies and some mechanical properties are then described.