The cluster [Fe4Cp4S6] as a ligand to Mo(II) and W(II)

Authors
Baker, PK Barclay, JE Clark, AI Evans, DJ Mitchell, K Richards, RL
Citation
Pk. Baker et al., The cluster [Fe4Cp4S6] as a ligand to Mo(II) and W(II), J ORGMET CH, 572(2), 1999, pp. 265-270
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
572
Issue
2
Year of publication
1999
Pages
265 - 270
Database
ISI
SICI code
0022-328X(19990115)572:2<265:TC[AAL>2.0.ZU;2-X
Abstract
The complexes [MI2(CO)(3)(Fe4Cp4S6-S,S')] {M = W (1) or Mo (2)}, [MI(SR)(CO )(3)(Fe4Cp4S6-S,S')] {R = Ph; M = W (3) or Mo (4): R = C6H2Me3-2,4,6; M = W (5) or Mo (6)}, [M(SR)(2)(CO)(3)(Fe4Cp4S6-S,S')] {R = SPh; M = W (7) or Mo (8): R = C6H2Me3-2,4,6; M = W (9) or Mo (10)}, [MI(CO)(3)(PPh3)(Fe4Cp4S6-S ,S')]I {M = W (11) or Mo (12)}, [M(CO)(3)(PPh3)(Fe4Cp4S6-S,S')]I-2 {M = W ( 13) or Mo (14)}, [M(CO)(3)(P-P)(Fe4Cp4S6-S,S')]I-2 {P-P = diphenylphosphino ethane (dppe); M = W (15) or Mo (16): P-P = diphenylphosphinopropane (dppp) ; M = W (17) or Mo (18)} and [WI(CO)(eta(2)-RC2R)(2)(Fe4Cp4S6-S,S')]I {R = Me (19) or Ph (20)} have been prepared. (C) 1999 Elsevier Science S.A. All rights reserved.