Some reactions of the ruthenium allenylidene complex [Ru(C=C=CPh2)(PPh3)(2)Cp][PF6] with nucleophiles

Authors
Bruce, MI Low, PJ Tiekink, ERT
Citation
Mi. Bruce et al., Some reactions of the ruthenium allenylidene complex [Ru(C=C=CPh2)(PPh3)(2)Cp][PF6] with nucleophiles, J ORGMET CH, 572(1), 1999, pp. 3-10
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
572
Issue
1
Year of publication
1999
Pages
3 - 10
Database
ISI
SICI code
0022-328X(19990105)572:1<3:SROTRA>2.0.ZU;2-O
Abstract
Reactions between [Ru(C=C=CPh2)(PPh3)(2)Cp][PF6] and nucleophilic reagents LiMe, NaOMe, KCN and KC5H5 have given the neutral substituted alkynyl-ruthe nium complexes Ru{C=CCPh2(Nu)} (PPh3)(2)Cp. The molecular structures of com plexes with Nu = OMe. CN and C5H5 have been determined. (C) 1999 Elsevier S cience S.A. All rights reserved.