Photolysis of the ion pair [eta(7)-(CHMo)-H-7-Mo-7(CO)(3)]+BPh4- induced by outer sphere charge transfer excitation

Authors
Kunkely, H Vogler, A
Citation
H. Kunkely et A. Vogler, Photolysis of the ion pair [eta(7)-(CHMo)-H-7-Mo-7(CO)(3)]+BPh4- induced by outer sphere charge transfer excitation, J ORGMET CH, 572(1), 1999, pp. 131-133
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
572
Issue
1
Year of publication
1999
Pages
131 - 133
Database
ISI
SICI code
0022-328X(19990105)572:1<131:POTIP[>2.0.ZU;2-E
Abstract
The electronic spectrum of the ion pair [eta(7)-C7H7Mo(CO)(3)]+BPh4- in CH2 Cl2 shows an outer sphere charge transfer (OSCT) absorption at lambda(max) = 370 nm. OSCT excitation yields [(eta(6)-C7H7Ph)Mo(CO)(3)] with phi = 0.02 at lambda = 405 nm. (C) 1999 Elsevier Science S.A. All rights reserved.