In this paper, the on-line optimization of batch reactors under parametric
uncertainty is considered. A method is presented that estimates the likely
economic performance of the on-line optimizer. The method of orthogonal col
location is employed to convert the differential algebraic optimization pro
blem (DAOP) of the dynamic optimization into a nonlinear program (NLP) and
determine the nominal optimum. Based on the resulting NLP, the optimization
steps are approximated by neighbouring extremal problems and the average d
eviation from the true process optimum is estimated dependent on the measur
ement error and the parametric uncertainty. The true process optimum is ass
umed to be represented by the optimum of the process model with the true pa
rameter values. A back off from the active path and endpoint inequality con
straints is determined at each optimization step which ensures the feasible
operation of the process. Based on the analysis results the optimal struct
ure of the optimizer in terms of measured variables and estimated parameter
s can be determined. The method of the average deviation from optimum is de
veloped for the fixed terminal time case and for time optimal problems. In
both cases, the theory is demonstrated on an example. (C) 1998 Elsevier Sci
ence Ltd. All rights reserved.