R. Sasai et al., Molecular alignment and photodimerization of 4 '-chloro-4-stilbenecarboxylic acid in hydrotalcite clays: Bilayer formation in the interlayers, LANGMUIR, 15(2), 1999, pp. 413-418
It was observed that the photolysis of 4'-chlorostilbenecarboxylic acid (CS
C) in N,N-dimethylformamide (DMF) yielded mainly a syn head-to-head dimer.
The molecular alignment in hydrotalcite interlayers has been investigated b
y electric linear dichroism (ELD) at room temperature in order to clarify t
he correlation between the photocyclodimerization and the molecular alignme
nt of CSC intercalated in hydrotalcite interlayers in DMF. ELD analysis in
combination with X-ray diffraction analysis of this hydrotalcite complex in
volving CSC revealed the CSC molecules to be intercalated as a double layer
, the tilt angle of the molecular plane being ca. 39.4 degrees. The suggest
ed molecular parallel packing model was found to be in good agreement with
the stereochemistry of the photodimerization.