Polymerisation of cyclic monomers, 8 - Synthesis and radical polymerisation of hybrid 2-vinylcyclopropanes

Authors
Moszner, N Volkel, T Fischer, UK Rheinberger, V
Citation
N. Moszner et al., Polymerisation of cyclic monomers, 8 - Synthesis and radical polymerisation of hybrid 2-vinylcyclopropanes, MACRO RAPID, 20(1), 1999, pp. 33-35
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
20
Issue
1
Year of publication
1999
Pages
33 - 35
Database
ISI
SICI code
1022-1336(199901)20:1<33:POCM8->2.0.ZU;2-Y
Abstract
Hybrid 2-vinylcyclopropanes were synthesised by the esterification of 1-met hoxycarbonyl-2- vinylcyclopropane-1-carboxylic acid with hydroxy group cont aining (meth)acrylates in the presence of 1,3- dicyclohexylcarbodiimide (DC C). The structure of the new hybrid monomers was confirmed by elemental ana lysis, IR, H-1 NMR and C-13 NMR spectroscopy. The radical polymerisation of the hybrid monomers in bulk with 2,2'-azoisobutyronitrile (AIBN) results i n transparent cross-linked polymers, whereas solution polymerisation partia lly results in soluble polymers with pendant 2-vinylcyclopropyl groups.