Head-on collision of droplets has been simulated using the method of molecu
lar dynamics. Recognizing that previous molecular dynamics simulations of t
his phenomenon have reported only coalescence or shattering outcomes, the r
esults reported show that actually the collision can result in either coale
scence or bouncing of the colliding droplets, although bouncing was observe
d only within a narrow band of state conditions. It was found that the ambi
ent gas plays a significant, though not essential role in effecting bouncin
g collision.