We have measured the photoluminescence (PL) spectra of GaAs/GaInP single qu
antum wells at pressure up to approximate to 5 GPa, and investigated the ch
aracteristics of the 1.46 eV deep emission band. It has a very long decay t
ime of several hundred nanoseconds. In addition, unlike the emission from t
he GaAs well, a strong blue-shift of its peak energy with excitation intens
ity is observed. With increasing pressure, the emission peak shows a sublin
ear shift towards higher energy, while the GaAs quantum well exhibits a lin
ear peak shift. The pressure dependence of the spectral peak position at hi
gher excitation intensity tends to reflect that of the adjacent 1.49 eV emi
ssion band which has a faster decay profile. The pressure-dependent PL beha
vior at lower excitation intensity is rather similar to those observed for
partially ordered GaInP alloys. These results suggest that the presence of
ordered GaInP layers plays an important role in the radiative recombination
at 1.46 eV and the deep emission is related to the transitions of electron
s and holes localized at the GaAs/ordered GaInP heterointerface.