Roughness-induced fluid interface fluctuations due to polar and apolar interactions

Citation
G. Palasantzas et G. Backx, Roughness-induced fluid interface fluctuations due to polar and apolar interactions, PHYS REV E, 59(1), 1999, pp. 1259-1262
Citations number
30
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
59
Issue
1
Year of publication
1999
Part
B
Pages
1259 - 1262
Database
ISI
SICI code
1063-651X(199901)59:1<1259:RFIFDT>2.0.ZU;2-E
Abstract
We investigate substrate roughness-induced fluctuations on liquid films in the presence of polar (exponential) and apolar (van der Waals) interactions in the complete wetting regime. The liquid/vapor interface roughness ampli tude sigma(w) increases rapidly with film thickness epsilon above a critica l thickness epsilon(c) for which the film is stable (or it does not rupture due to presence of polar interactions), and it reaches a maximum at a thic kness epsilon(m) slightly larger than epsilon(c) if polar and apolar compon ents are of comparable strength and for small polar potential ranges. As th e strength of the polar interaction decreases with respect to the apolar; b ehavior characteristic of that of apolar interactions within the Derjaguin approximation is recovered for moderate film thicknesses (epsilon > epsilon (m)); sigma(w)proportional to zeta(-2) with zeta the healing length. [S1063 -651X(99)11701-X].