Ultracold potassium molecules are produced in the X (1)Sigma(g)(+) electron
ic ground state by photoassociation in a magneto-optical trap. They are det
ected sensitively and selectively by use of two-color resonant ionization,
followed by time-of-flight mass spectroscopy. We observe deeply bound molec
ules with nu congruent to 36, at a temperature of about 300 mu K. Presently
about 1000 molecules/sec are produced, and much higher production rates sh
ould be attainable in the future.