Blends of polycaprolactone with polyvinylalcohol: a DSC, optical microscopy and solid state NMR study

Blend films of polycaprolactone (PCL) and polyvinylalcohol (PVAl) have been obtained by evaporation of a solution of both components in hexafluoroisop ropanol. The miscibility of the polymers in the amorphous part of the blend has been studied by conventional methods (optical microscopy. DSC and FTIR ) and by solid state NMR. Phase separation is observed in the melt. The abs ence of any lowering of Tm and the presence of one low temperature Tg near that of pure PCL support the hypothesis of phase separation in the amorphou s part of the blend. However, various experimental data suggest the presenc e of some type of physical interactions between components. These data are: the important decrease of PCL crystallinity in the blend, the morphology o f PCL spherulites after crystallization at 45 degrees C and the absence upo n annealing the blend at 50 degrees C, of any rearrangement of PCL crystall ites into spherulites as observed in pure PCL. The measurement of proton sp in-lattice relaxation time T-1 by solid state NMR using cross polarization ha, shown that the components are compatible at the scale of 60-90 nm and a re thus very finely dispersed into each other. (C) 1999 Elsevier Science Lt d. All rights reserved.