Study of the catalytic activity of electrochemically reduced forms of phthalocyanines in the reaction of CO2 with epoxides

Citation
Tv. Magdesieva et al., Study of the catalytic activity of electrochemically reduced forms of phthalocyanines in the reaction of CO2 with epoxides, RUSS CHEM B, 47(11), 1998, pp. 2137-2145
Citations number
32
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
11
Year of publication
1998
Pages
2137 - 2145
Database
ISI
SICI code
1066-5285(199811)47:11<2137:SOTCAO>2.0.ZU;2-4
Abstract
Catalytic activity of electrochemically reduced forms of mono- and diphthai ocyanine complexes of transition and rare-earth elements in the reaction of carbon dioxide with epoxides is considerably higher than that of correspon ding neutral forms. The catalytic efficiency depends on the nature of the p hthalocyanine complex, the method of the catalyst immobilization, and the e lectrophilicity of epoxide.