Synthesis and molecular structure of the complex YbI(bipy)(DME)(2)

Authors
Petrovskaya, TV Fedyushkin, IL Nevodchikov, VI Bochkarev, MN Borodina, NV Eremenko, IL Nefedov, SE
Citation
Tv. Petrovskaya et al., Synthesis and molecular structure of the complex YbI(bipy)(DME)(2), RUSS CHEM B, 47(11), 1998, pp. 2271-2273
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
11
Year of publication
1998
Pages
2271 - 2273
Database
ISI
SICI code
1066-5285(199811)47:11<2271:SAMSOT>2.0.ZU;2-6
Abstract
The reaction of the naphthalene complex of ytterbium, [Yb(DME)(2)](2)(mu-C1 0H8) with 2,2'-bipyridine in 1,2-dimethoxyethane afforded the Yb-II complex containing the 2,2'-bipyridine radical anion. The resulting complex YbI(bi py)(DME)(2) was characterized by IR and ESR spectroscopy, X-ray diffraction analysis, and magnetochemistry.