Electronic structure of 10-alkyl(aryl)phenoxarsines and the mechanism of their reactions with methyl iodide

Authors
Mukhutdinov, EA Kuznetsov, AM Mukhutdinov, AA Gavrilov, VI Garieva, FR
Citation
Ea. Mukhutdinov et al., Electronic structure of 10-alkyl(aryl)phenoxarsines and the mechanism of their reactions with methyl iodide, RUSS CHEM B, 47(11), 1998, pp. 2298-2299
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
11
Year of publication
1998
Pages
2298 - 2299
Database
ISI
SICI code
1066-5285(199811)47:11<2298:ESO1AT>2.0.ZU;2-9
Abstract
The structure of 10-alkyl(aryl)phenoxarsines has been investigated by the s emiempirical quantum-chemical PM3 method. The As-III atom has a positive ch arge and simultaneously exhibits nucleophilic properties in the reaction wi th methyl iodide. The reactions of 10-alkyl(aryl)phenoxarsines with methyl iodide are probably controlled by charge distribution.