Oxidative decarboxylation of cyclohexanecarbaldehyde in the presence of cyclooctane catalyzed by a binuclear manganese(IV) complex

Authors
Lindsay-Smith, JR Shul'pin, GB
Citation
Jr. Lindsay-smith et Gb. Shul'Pin, Oxidative decarboxylation of cyclohexanecarbaldehyde in the presence of cyclooctane catalyzed by a binuclear manganese(IV) complex, RUSS CHEM B, 47(11), 1998, pp. 2313-2315
Citations number
20
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
11
Year of publication
1998
Pages
2313 - 2315
Database
ISI
SICI code
1066-5285(199811)47:11<2313:ODOCIT>2.0.ZU;2-V
Abstract
On heating, a Mn-IV complex initiates oxidation of cyclohexanecarbaldehyde with atmospheric oxygen in MeCN resulting in the formation of cyclohexaneca rboxylic acid and considerable amounts of oxidative decarboxylation product s (cyclohexane, cyclohexanol, and cyclohexanone). Cyclooctanol and cyclooct anone are also formed in the presence of cyclooctane.