B. Salazar-hernandez et al., Observation of zinc-blende to diamond transition in metastable (GaAs)(1-x)(Ge-2)(x) alloys by Raman scattering, SOL ST COMM, 109(5), 1999, pp. 295-300
Epitaxial metastable (GaAs)(1-x)(Ge-2)(x) thin films throughout most of the
full compositional x range were studied by Raman scattering. From the feat
ures observed in the compositional dependence of the ratio Gamma(a)/Gamma(b
) of the LO-like mode and that between the integrated intensities of the fo
rbidden TO-like mode and of the allowed LO-like mode, we get direct evidenc
e for the zincblende to diamond structural transition, which is observed to
occur at x approximate to 0.35. Results are in good agreement with X-ray d
iffraction data. (C) 1999 Elsevier Science Ltd. Ail rights reserved.