O. Sellier et al., Ring closing metathesis as an efficient approach to branched cyclitols andaminocyclitols: a short synthesis of valiolamine, TETRAHEDR L, 40(5), 1999, pp. 853-856
Ring closing metathesis of sugar-derived 1,6 dienes is the key step for the
construction of highly functionnalized cyclohexenes, precursors of branche
d cyclitols and aminocyclitols. The method has been used for a short synthe
sis of valiolamine. (C) 1999 Elsevier Science Ltd. All rights reserved.