Interaction of hydrocarbons with partial oxidation catalysts

Citation
Ly. Margolis et Vn. Korchak, Interaction of hydrocarbons with partial oxidation catalysts, USP KH, 67(12), 1998, pp. 1175-1185
Citations number
150
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
67
Issue
12
Year of publication
1998
Pages
1175 - 1185
Database
ISI
SICI code
0042-1308(1998)67:12<1175:IOHWPO>2.0.ZU;2-N
Abstract
Interaction of differently constructed hydrocarbons with partial oxidation catalysts was studied. It was shown that during activation of organic molec ule on the surface the formation of adsorbed complexes or radicals can take place. This process depends on the: structure of hydrocarbon molecules, bo nd energy, temperature and the nature of solid surface (structure, valent s tate of elements contained in its composition, oxygen forms and their mobil ity). The possible mechanism of the activation of hydrocarbons on different systems is discussed.