Interaction of differently constructed hydrocarbons with partial oxidation
catalysts was studied. It was shown that during activation of organic molec
ule on the surface the formation of adsorbed complexes or radicals can take
place. This process depends on the: structure of hydrocarbon molecules, bo
nd energy, temperature and the nature of solid surface (structure, valent s
tate of elements contained in its composition, oxygen forms and their mobil
ity). The possible mechanism of the activation of hydrocarbons on different
systems is discussed.