Wj. Wu et Gh. Nancollas, Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods, ADV COLL IN, 79(2-3), 1999, pp. 229-279
Methods for the determination of interfacial tension between a solid and a
liquid are reviewed including solubility/particle size, crystallization and
dissolution kinetics. The use of solubility as a function of particle size
, originally put forward by Ostwald and later corrected by Freundlich, may
be unjustified for determining interfacial tension at solid-liquid interfac
es. The interfacial tension values between solutions and sparingly soluble
minerals such as hydroxyapatite, fluorapatite, brushite, octacalcium phosph
ate, calcium oxalate monohydrate, barium sulfate, calcium sulfate, calcite,
and divalent metal fluorides are discussed. A comparison of these results
is made with contact angle or wetting measurements. The interfacial tension
values obtained from constant composition reaction kinetics are of the sam
e order of magnitude as those determined using a contact angle method invol
ving thin layer wicking techniques. (C) 1999 Elsevier Science B.V. All righ
ts reserved.