Syntheses and structures of quinuclidine-stabilized four- and five-coordinate mono- and di-chlorogallane

Authors
Luo, B Young, VG Gladfelter, WL
Citation
B. Luo et al., Syntheses and structures of quinuclidine-stabilized four- and five-coordinate mono- and di-chlorogallane, CHEM COMMUN, (2), 1999, pp. 123-124
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
1999
Pages
123 - 124
Database
ISI
SICI code
1359-7345(19990121):2<123:SASOQF>2.0.ZU;2-2
Abstract
Hydride/chloride redistribution reactions provided high yields of GaCl2H(qu in) I, GaCl2H(quin)(2) II, GaClH2(quin) III and GaClH2(quin)(2) IV(quin = q uinuclidine) and structural characterization of compounds II and IV authent icate the unusual five-coordinate geometry for gallium hydride complexes.