Phosphorus octaethyltetraphenylporphyrins [(oetpp)P(Me)(X)]PF6 (X = Me, OH, F) having saddle (X = Me) or ruffled (X = OH, F) conformations

Authors
Yamamoto, A Satoh, W Yamamoto, Y Akiba, KY
Citation
A. Yamamoto et al., Phosphorus octaethyltetraphenylporphyrins [(oetpp)P(Me)(X)]PF6 (X = Me, OH, F) having saddle (X = Me) or ruffled (X = OH, F) conformations, CHEM COMMUN, (2), 1999, pp. 147-148
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
1999
Pages
147 - 148
Database
ISI
SICI code
1359-7345(19990121):2<147:PO[(=M>2.0.ZU;2-O
Abstract
X-Ray crystallographic structures of [(oetpp)P(Me)(X)]PF6 revealed that the axial ligand (X) plays a major role in changing the conformation of the po rphyrin core from saddle(X = Me) to ruffled (X = OH and F).