M. Muneer et al., PHOTOCATALYTIC DEGRADATION OF WASTE-WATER POLLUTANTS - TITANIUM DIOXIDE-MEDIATED OXIDATION OF A TEXTILE DYE, ACID BLUE-40, Research of chemical intermediates, 23(3), 1997, pp. 233-246
The photocatalyzed degradation of Acid Blue 40, a textile dye, in aque
ous suspension of TiO2 has been studied by monitoring the change in dy
e concentration and formation of carbon dioxide as a function of irrad
iation time. Mechanistic studies suggest that in addition to the react
ion of the hydroxyl and superoxide radicals with the dye, electron tra
nsfer from the photoexcited TiO2 to the dye forms a significant pathwa
y in the photodegradation process.