Sheet polymer and its complexes: Part III - Synthesis and conductive properties of polymeric tetraphenylporphyrin and its complexes

Citation
Yp. Wang et al., Sheet polymer and its complexes: Part III - Synthesis and conductive properties of polymeric tetraphenylporphyrin and its complexes, I J CHEM B, 37(10), 1998, pp. 1034-1036
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
37
Issue
10
Year of publication
1998
Pages
1034 - 1036
Database
ISI
SICI code
0376-4699(199810)37:10<1034:SPAICP>2.0.ZU;2-X
Abstract
The polymeric porphyrin film has been prepared by polymerization of terepht halaldehyde with pyrrole. The spectra and electrical properties of its comp lexes with transition metals (Cu, Co, Zn, Fe, Mn, Ni) have been discussed. The polymer exhibits semi-conducting property (sigma(rt)=5.08 x 10(-8)-4.44 x 10(-3) s/cm) after doping with iodine.