Spectrum of fast dynamics in glass forming liquids: Does the "knee'' exist?

Citation
J. Gapinski et al., Spectrum of fast dynamics in glass forming liquids: Does the "knee'' exist?, J CHEM PHYS, 110(5), 1999, pp. 2312-2315
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
5
Year of publication
1999
Pages
2312 - 2315
Database
ISI
SICI code
0021-9606(19990201)110:5<2312:SOFDIG>2.0.ZU;2-O
Abstract
A knee-shaped feature observed earlier in light scattering spectra of Ca0.4 K0.3(NO3)(1.4) (CKN) below T-c is used as a strong argument in favor of mod e- coupling theory of the glass transition (MCT). Our careful measurements reveal no "knee" in the spectra of two glass forming liquids, CKN and ortho - terphenyl. Instead of the knee the spectra show nontrivial broadening and an increase of the intensity with a temperature increase. Both variations are confirmed by neutron scattering measurements on CKN and are neither exp ected in the asymptotic MCT predictions nor in any other model. (C) 1999 Am erican Institute of Physics. [S0021-9606(99)51605-X].