Nylon 6 as a modifier for maleated ethylene-propylene elastomers

Citation
O. Okada et al., Nylon 6 as a modifier for maleated ethylene-propylene elastomers, POLYMER, 40(10), 1999, pp. 2699-2709
Citations number
55
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861 → ACNP
Volume
40
Issue
10
Year of publication
1999
Pages
2699 - 2709
Database
ISI
SICI code
0032-3861(199905)40:10<2699:N6AAMF>2.0.ZU;2-Q
Abstract
Blends of nylon 6 and ethylene-propylene rubber, grafted with maleic anhydr ide, (EPR-g-MA) were prepared using a melt blending process. For certain co mpositions, nylon 6 forms finely dispersed particles due to the reaction of the polyamide amine end groups with the grafted maleic anhydride, that hav e the potential to reinforce the elastomer matrix. This study focuses on th e effects of the content of nylon 6 on the rheological, morphological and m echanical properties of such blends where nylon 6 is the dispersed phase. T ransmission electron microscopy was used to determine blend morphology. Mec hanical properties were examined by stress-strain measurements and dynamic mechanical thermal measurements; the modulus is compared to values calculat ed from theory. The addition of magnesium oxide causes significant improvem ent in tensile properties of these blends. (C) 1999 Published by Elsevier S cience Ltd. All rights reserved.