Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes.

Authors
Bouyssi, D Monteiro, N Balme, G
Citation
D. Bouyssi et al., Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes., TETRAHEDR L, 40(7), 1999, pp. 1297-1300
Citations number
29
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
7
Year of publication
1999
Pages
1297 - 1300
Database
ISI
SICI code
0040-4039(19990212)40:7<1297:ICROUA>2.0.ZU;2-I
Abstract
The copper-promoted cycloisomerization of unsaturated alkynes bearing a sta bilized nucleophile is described, providing a novel synthesis of various ir idoid monoterpenes. (C) 1999 Elsevier Science Ltd. All rights reserved.