mu-Pyrazine-N : N '-bis[aqua(N-salicylidene-glycinato-O,N,O ')copper(II)] dihydrate

Authors
Citation
Sa. Warda, mu-Pyrazine-N : N '-bis[aqua(N-salicylidene-glycinato-O,N,O ')copper(II)] dihydrate, ACT CRYST C, 54, 1998, pp. 1756-1758
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1756 - 1758
Database
ISI
SICI code
0108-2701(199812)54:<1756:M:N''D>2.0.ZU;2-8
Abstract
The title compound, [Cu-2(C9H7NO3)(2)(mu-C4H4N2)-(H2O)(2)]. 2H(2)O, adopts a square-pyramidal copper(II) coordination with three donor atoms of the N- salicylideneglycinato Schiff base dianion and one N atom of the pyrazine li gand bound in the basal plane. The axial position is occupied by a water O atom at a distance of 2.436 (2) Angstrom. The molecules are connected throu gh the second N atom of the pyrazine to form binuclear copper units. The wa ter molecules form a hydrogen-bonding network between the dicopper molecule s.