Bis(dimethylammonium) pentachloroantimonate(III), on the deformation of the octahedral coordination of Sb-III

Authors
Bujak, M Zaleski, J
Citation
M. Bujak et J. Zaleski, Bis(dimethylammonium) pentachloroantimonate(III), on the deformation of the octahedral coordination of Sb-III, ACT CRYST C, 54, 1998, pp. 1773-1777
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1773 - 1777
Database
ISI
SICI code
0108-2701(199812)54:<1773:BPOTDO>2.0.ZU;2-Q
Abstract
The structure of the title compound, [NH2(CH3)(2)](2-)[SbCl5], was determin ed at 295 and 85 K. It consists of polymeric (SbCl52-)(n), chains composed of deformed SbCl63- octahedra connected by corners and dimethylammonium cat ions. The temperature dependence of the Sb-Cl bond lengths is discussed. It is argued that the deformation of the octahedral coordination of the Sb-II I atom is caused by electrostatic interaction/hydrogen bonds.